Titanium Dioxide Utilisation

The aim of this project was to enable paint formulators to improve utilisation of titanium dioxide. Four subject areas were selected after discussion with industry. These are:

Computer Prediction of Scattering: Using input from project sponsors and published literature, PRA produced a PC based program for calculating the optical properties of coatings films from fundamental parameters such as pigment refractive index and size distribution

The Effect of Polymer Refractive Index: The significance of binder refractive index is often ignored in estimates of light scattering. However, calculation of reflectivity of TiO2 in different binders indicate that significant improvements in scattering could be obtained by careful binder selection. This hypothesis was explored and a database of binder refractive indices produced.

Characterisation of Pigment - Dispersant Interaction: Measurement of acid base characteristics of TiO2 surfaces and dispersants provide a method to select suitable TiO2 - dispersant pairs with minimal experimentation. Various methods of measuring acid base character of pigments and dispersants were explored and correlation with absorbtion of dispersant was investigated.

Determination of State of Dispersion of Titanium Dioxide in the Wet: An instrument based on the Pfund cryptometer but using a photoelectric cell instead of the human eye has been developed in collaboration with a Rhopoint Instrumentation.

Further Information

If you are interested in this, or any other project, please contact Richard Holman.

Partners

Industrial Advisory Group

Funding

Industrial Advisory Group

Code: TIO2
Status: Completed
Duration: 2 Years
Reports: All PRA Members