The three main classes of microorganisms that can colonise
paints are
Fungi
Algae
Bacteria
All microorganisms need both water and nutrients and some,
like algae, also need sunlight.
Microorganisms have the potential to grow in liquid paint
before it is applied and also on paint films after application.
Paint manufacturers may use biocides in their products in order
to prevent these organisms developing. The biocides that are used
for this purpose can be divided into two main classes:-
In-can biocides designed to prevent the growth of
microorganisms during storage.
Paint film biocides designed to prevent the growth of
microorganisms on applied paint films.
These biocides can be further sub-divided into those which
have anti-fungal, anti-algal and anti-bacterial properties.
Bio-degradation of Liquid Coatings
The requirement of algae for sunlight means they cannot grow
in closed containers of liquid paint. Fungi and bacteria both
require water and consequently neither can grow in solvent based
coatings. This means that in-can biocides do not need to be added
to solvent-borne products.
Water-borne coatings however are potentially prone to in-can
attack by both bacteria and fungi . If these organisms develop,
they can cause a number of problems including:-
viscosity loss
malodour
discolouration
gassing
frothing
sedimentation
pH change
Bio-degradation of Applied Coatings
Fungi, algae and bacteria can all grow on applied paint films
and solvent and water based coatings are both susceptible. The
effect of each class of organism depends on the film environment
:-
Fungal Growth on Paint Films
Fungus (otherwise known as mould or mildew) requires no
sunlight and only minimal amounts of water in order to grow.
Consequently it will develop on any paint surface which is
periodically moist and which can provide sufficient nutrients. In
practice this means that, in the absence of a fungicide, all
external coating films are liable to fungal colonisation unless
they are located in very dry situations.
The relatively dry conditions inside buildings do not favour
fungal growth and that which does occur is normally restricted to
paint surfaces which are periodically wet. Typically this means
surfaces in kitchens and bathrooms where condensation forms.
Fungal growth on a paint film normally appears as dark spots
on the surface and is sometimes confused with dirt. As well as
disfiguring the surface, the organism can actually penetrate the
film and make it more permeable to water. Growth can also develop
under the film and cause loss of adhesion.
Fungal organisms reproduce by producing spores and these can
be a significant health hazard to persons with respiratory
allergies.
Algal Growth on Paint Films
In order to grow, algae need sunlight and a surface which can
provide nutrients and is almost permanently wet. This means that
algal growth does not occur on interior paint films and is
normally only seen externally on coatings in very wet
environments. In situations outside the tropics, a typical
example of a favoured environment would be a paint film in a
shaded area of a building which was wetted by a leaking gutter.
Algal growth appears as an unsightly greenish slime. The
actual damage that the organism does to paintwork is probably
minimal but its presence is a visual indication of very high
moisture levels. It is a particularly unwelcome sight on painted
wood because the level of moisture present will almost certainly
mean that the underlying wood is rotting.
Bacterial Growth on Paint Films
Bacterial growth on a paint film is not visible to the naked
eye and it does not cause any significant damage to the film.
Consequently, as a general rule, when paint manufacturers add
anti-bacterial agents, they do so with the sole intention of
preventing in-can degradation.
An important exception to this rule is a relatively new class
of paints known as hygienic coatings. These are designed for use
in locations such as food preparation areas and hospitals where
it is important to limit the growth of bacteria on interior
surfaces.
In areas where there is a high level of moisture in the
atmosphere, bacteria can multiply rapidly. Even the very act of
washing a wall produces a surface that, during the drying period,
is susceptible to bacterial colonisation. Hygienic coatings can
provide protection under these conditions.
Services
PRA provides a service specialising in all aspects of
microbiology relating to the coatings industry, and is able to
carry out a wide range of standard and in-house test methodology.
These include:-
Contract research
Troubleshooting investigations
Comparative evaluation of biocides
Evaluation of materials for fungal, bacterial and algal
resistance
Investigation of microbial contamination
Microbial assessment of hygienic coatings
Test Methods
These test methods can be sub-divided into those applicable to
liquid coatings and those for dry films. In addition to paints we
can also test adhesives, boards, electrical and electronic
equipment etc.
Microbial Resistance Testing of Liquid Paints
Test
Standard
Bacterial Resistance
In-house method
Bacterial Resistance
ASTM D 2574
Fungal Resistance
In-house method
Microbial Resistance Testing of Paint Films
Test
Standard
Fungal Resistance
BS 3900-G6
Fungal Resistance
VdL-RL 06
Algal Resistance
BBA MOAT No 33
Algal Resistance
VdL-RL 07
Anti-bacterial Activity of Hygienic Coatings
JIS Z 2801
Microbial Resistance Testing of Miscellaneous Materials
Test
Standard
Fungal Resistance: Building Materials
BS 1982 Part 3
Fungal Resistance: Ceramic Tile Adhesives
BS 5980
Fungal Resistance: Wallpaper Adhesives
BS 3046
Fungal Resistance: Electrical and Electronic
Equipment